The two processes sr and pox occur simultaneously in the presence of. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. This autothermal reactor consists of two concentric tubes. Hence, it has been the focus of research in the past few years. Autothermal reforming or oxidative steam reforming is a combination of conventional steam reforming of the fuel endothermic reaction with the partial oxidation of a small amount of the fuel exothermic reaction in order to achieve an autothermal reaction that proceeds without external input of energy chang et al. The reactor, preheated with air and steam from the feed delivery system, lit off and performed autothermally without the need for external heating. Autothermal reforming of natural gas to synthesis gas. Describes the operation and the equations used to model an autothermal reactor. Determine catalyst performance h 2 yield, co x selectivity, hydrocarbon breakthrough, fuel conversion.
A novel reactor concept with autothermal operation is presented for the simultaneous production of ethylene by oxidative coupling ocm and synthesis gas by steam reforming of methane srm. Optimization of a methane autothermal reforming bas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r. The integration of mixed ionic electronic conducting miec membranes for air separation in a smalltomedium scale unit for h2 production in the range of 650850 nm3h via autothermal reforming of methane has been investigated in the present study. The study of chemical reaction engineering cre combines the study of chemical kinetics with the reactors in which the reactions occur. Producing hydrogen from jeta fuel in a reactor with. Steam srm and autothermal atr reforming of methane processes were evaluated through thermodynamical and stoichiometric analyses that benefit hydrogen production, using. If we consider the countercurrent heat exchanger of fig. Autothermal reforming of methane with integrated co 2 capture in a novel fluidized bed membrane reactor. The model defines two subsequent sections in the reactor. Onboard h2 production is proposed as a possible solution to these problems, especially in the case of considering renewable feedstocks. Autothermal reforming of methane with integrated co.
Our different reforming layouts can be tailormade to meet the requirements of the client without compromising on reliability. Integrated autothermal reactor concepts for oxidative coupling and reforming of methane. Hydrogen production by autothermal reforming of ethanol. Hydrogen production from methane autothermal reforming. However, as atr and pox reactors require pure oxygen, steam reforming is nowadays considered the more economic option. Mann prepared by sandia national laboratories albuquerque, new mexico 87185 and livermore, california 94550 sandia is a multiprogram laboratory operated by sandia corporation. In this work, an integrated fuel processor, including a mixing zone, an atr reactor, a wgs reactor and two recuperators was fabricated and the hydrogen. Heat exchange reforming is explored by several parties as a means of improving the processes for production of synthesis gas for gtl units and other purposes. The atr ah2 makes use of an additional enthalpy flow coming from a flow of steam, which was generated in the catalytic burner of the fuel cell system. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. The concepts use heat available in the process gas downstream an atr for steam reforming in a heat exchanger type of reactor.
Autothermal reforming of natural gas to synthesis gas reference. Molecules free fulltext autothermal reforming using. The standard reactor design for an autothermal fixedbed reactor consists of an adiabatic fixed bed of catalyst which is connected with a heat exchanger so that the hot reactor effluent heats up the cold feed. Autothermal reforming of methane with integrated co2.
Hydrogen, as an energy carrier, can take the main role in the transition to a new energy model based on renewable sources. Autothermal reforming of methane with integrated co 2. An exothermic reaction in the catalyst bed raises the gas temperature and heat transfers from the catalyst bed. The structuring of the catalytic functions inside a single catalyst. Autothermal reforming atr syngas generation air liquide. N2 two fluidized bed membrane reactor concepts for hydrogen production via autothermal reforming of methane. Advanced modelling and optimisation of natural gas.
The autothermal reforming reactor consists of three zones. The reaction is strongly endothermic consumes heat. Design and performance of a kw scale reformer using pure oxygen as oxidant article pdf available january 2006 with 1,892 reads how we measure reads. Hydrogen production by autothermal reforming of ethanol over monolith reactors. Effect of catalytic cylinders on autothermal reforming of. Hydrogen h 2 is currently used mainly in the chemical industry for the production of ammonia and methanol. The first section of ptal2o3 catalyst is designed for oxidation reaction, whereas the second one involves steam reforming reaction based on nimgal2o4 catalyst. D stationary reactor model describes the catalytic conversion of a gaseous hydrocarbon fuel with air and steam to synthesis gas by autothermal reforming and catalytic partial oxidation. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated. Autothermal reforming of methane in membrane assisted.
Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Hydrogen as a chemical element h is the most widespread one on the earth and as molecular dihydrogen h 2 can be obtained. Preliminary modeling and design of an autothermal reformer. Ultrapure hydrogen is obtained via hydrogen permselective pdbased membranes, while the required reaction energy is supplied by oxidizing part of the ch4 in situ in the methane combustion configuration or by combusting part of the. To avoid this problem, autothermal reforming atr is suggested in which the thermal effects of pox and sr reactions are combined by feeding the fuel, water, and air together into the reactor. Nevertheless, in the near future, hydrogen is expected to become a significant fuel that will largely contribute to the quality of atmospheric air. Significant co2 production was detected during catalyst lightoff transitory, which sheds light in the lightoff mechanism for jp8 autothermal reforming. Investigation of a dualbed autothermal reforming of. The main purpose of this technology is hydrogen production. Autothermal reforming of methane on rhodium catalysts. Hydrogen production via autothermal reforming atr is particularly attractive for applications that demand a quick startup and response time in a compact size. Membranes based on mixed ionic electronic conducting oxides such as ba0. Microkinetic analysis for model reduction marm dixita, renika baruaha, dhrupad parikha, sudhanshu sharmaa, atul bhargava,1 aenergy systems laboratory, iit gandhinagar, ahmedabad, gujarat, india abstract methane autothermal reforming has been studied using comprehensive, detailed microkinetic.
T1 autothermal reforming of methane with integrated co2 capture in a novel fluidized bed membrane reactor. One of the most attractive benefits of autothermal reforming of hydrocarbon fuels is the possibility of selfsustainability of the reaction if the process is carefully managed and designed. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Autothermal fixedbed reactor concepts sciencedirect. Autothermal reactor wolfram demonstrations project. In any manufacturing process where there is a chemical change. The reactants are at temperature when they enter the inner tube, which is a packed catalyst bed, where they flow left to right.
Autothermal reforming an overview sciencedirect topics. Lecture 9 reactor sizing chemical kinetics is the study of chemical reaction rates and reaction mechanisms. The results show that larger cylinder radius can promote reforming reaction. Optimization of a methane autothermal reformingbased. An ebook reader can be a software application for use on a computer such as microsofts free reader application, or a book sized computer this is used solely as a reading device such as nuvomedias rocket ebook. Autothermal reforming atr is a process for producing syngas, composed of hydrogen and carbon monoxide, by partially oxidizing a hydrocarbon feed with oxygen and steam and subsequent catalytic reforming. Reformer, temperature control, autothermal, methanol, copperzinc oxide catalyst 1.
Thermodynamic assessment and autothermal reactor design article pdf available in journal of natural gas science and engineering 16. Basic objectives in design of a reactor in chemical engineering physical operations such as fluid flow, heat transfer, mass transfer and separation processes play a very large part. The catalyst showed mechanical stability but activity in terms of methane conversion showed a decrease in activity over time. Hence, most of these plants are based on steam reforming although several plants based on partial oxidation reactors are still in use. Matosa, stepan spatenkab a chemical engineering department, instituto superior tecnico, lisbon, portugal b process systems enterprise ltd.
However, its application in the transport sector is limited by its difficult storage and the lack of infrastructure for its distribution. Two fluidized bed membrane reactor concepts for hydrogen production via autothermal reforming of methane with integrated co2 capture are proposed. A one dimensional, nonisothermal reactor model was employed. Optimization of a methane autothermal reformingbas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r. If this is valid for larger capacities in excess of 100,000. Our wellknown side fired reforming furnaces, specialized secondary reformer burners and high active reforming catalysts all contribute to improving the operation of. Develop advanced autothermal reforming atr catalysts that meet doe targets for the fast start reformer 9gashourly space velocity ghsv. The feed enters an annular region between the tubes at temperature and flows from right to left. Autothermal cyclic reforming and h2 refueling system.
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